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Registros recuperados: 54
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La contamination par le cadmium en Gironde et son extension sur le plateau continental ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois.
La répartition du cadmium dans l'eau, le sédiment et la matière en suspension de la Gironde, du proche plateau cohtinental et de la baie de Marennes-Oléron a été étudiée lors de trois campagnes réalisées en conditions de débits moyens ou d'étiage de la Garonne et de la Dordogne. Des apports anormaux de cadmium particulaire par la Garonne ont été mis en évidence. Après désorption ou solubilisation, ils sont expulsés sous forme dissoute, formant un panache très net mais peu étendu en dehors duquel les concentrations en cadmium dissous sont conformes aux valeurs habituellement observées en milieu côtier. Les teneurs en cadmium dissous du bas estuaire expliquent les fortes concentrations relevées dans les huîtres de ce secteur. Le caractère récent de la...
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Ano: 1986 URL: http://archimer.ifremer.fr/doc/00105/21583/19163.pdf
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Mise au point d'un test microcrustacé marin ArchiMer
Marcaillou-le Baut, Claire; Le Dean, Loic; Chiffoleau, Jean-francois; Sanjuan, Jane.
Because of the low number of currently available toxicity tests for marine environment, the authors describe an experimental procedure using a marine copepod : Tigriopus brevicornis. This method can be used to quantify the 50 % inhibition of larval production or growth. The variability in controls larval production reaches about 9 %. The toxicity of two contaminants : tributyltin (TBTF) and cadmium chloride (CdCl2) was determined with this method and the 50 % decreases in larval production are respectively 1,4 µg/l (TBTF) and 61 µg/l (Cd++).
Tipo: Text Palavras-chave: Test; Toxicité; Copépode; Étain; Cadmium; Test; Toxicity; Copepod; Tin; Cadmium.
Ano: 1988 URL: http://archimer.ifremer.fr/doc/00139/25036/23145.pdf
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La contamination de la Gironde par le cadmium : origine, extension, importance ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois; Jouanneau, Jean-marie; Latouche, Claude; Philipps, Isabelle.
In 1979, the French monitoring program RNO (Réseau National d'Observation de la qualité du milieu Marin) pointed out a dramatic cadmium contamination in the oysters from the Gironde estuary (up to 100 ug -1, dry weight). The wild oyster-beds upstream the estuary were shown to be the most contaminated. This result tends to point to the river as the source of the cadmium contamination. At the same rime, uncontaminated oysters from Arcachon were transplanted in the Gironde estuary (La Fosse, Dau). This ex periment confirmed the importance and proved the permanence of the contamination. Very high concentrations of dissolved cadmium (400 ng. 1-1) were measured in the estuarine mixing zone. This phenomenon can be explained by the desorption of cadmiumfrom...
Tipo: Text Palavras-chave: Cadmium; Désorption; Estuaire; Bilan géochimique; Contamination des huîtres; Cadmium; Desorption; Estuary; Geochemical budget; Oyster contamination.
Ano: 1989 URL: http://archimer.ifremer.fr/doc/00167/27820/26013.pdf
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Influence des rejets urbains sur la contamination de la rivière de Morlaix par les métaux ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois; Gonzalez, Jean-louis; Noel, Joelle.
Raw and processed outflow from the Morlaix city sewage treatment plant were monitored every fourth hour for a 24 hours period, and monthly for eight months. The urban Hg, Cd, Cu, Zn and Pb outflow was shown to be much less than the river-borne flux. Sediments from the catchment area and estuary show that the influence of the town on the metal concentrations is limited to the harbour basin. The metal concentations are essentially controlled by granulometry.
Tipo: Text Palavras-chave: Métaux; Sédiment; Rivière de Morlaix.
Ano: 1990 URL: http://archimer.ifremer.fr/doc/00167/27793/25986.pdf
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Distribution of Cd and Hg in the Bay of Marennes-Oléron ArchiMer
Gonzalez, Jean-louis; Boutier, Bernard; Chiffoleau, Jean-francois; Auger, Dominique; Noel, Joelle; Truquet, Isabelle.
The study of Cd and Hg distribution in the sediments, water and suspended matter of the Bay of Marennes-Oléron provided the opportunity to identify the factors governing the distribution of these two contaminants throughout the bay. On one hand, these elements are associated with the continental inputs from the Charente river which settle on arrivaI at the mouth of the estuary and in the eastern part of the bay. The Cd and Hg present in these deposits are associated with POC, as weIl as with Mn and Fe oxides and hydroxides. On the other hand, a portion of the dissolved inputs is recycled in the bay waters through phytoplankton activity. This mechanism contributes, particularly in the case of Cd, to increased particulate metal fluxes from the water column...
Tipo: Text Palavras-chave: Baie de Marennes-Oléron; Métaux lourds; Sédiments; MES; Activité phytoplanctonique; BAY OF MARENNES-OLERON; HEAVY METALS; SEDIMENTS; SUSPENDED MATTER; PHYTOPLANKTON ACTIVITY.
Ano: 1991 URL: http://archimer.ifremer.fr/doc/00085/19604/17242.pdf
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Monitoring of pollutant biochemical effects on marine organisms of the french coasts ArchiMer
Galgani, Francois; Bocquene, Gilles; Truquet, Philippe; Burgeot, Thierry; Chiffoleau, Jean-francois; Claisse, Didier.
The establishment of a network to assess pollutant effects is a current concern of international bodies such as the North Sea Task Force, the International Council for the Exploration of the Sea and the Intergovernmental Oceanographic Commission. With respect to the French coasts, three major considerations have been defined : the choice of monitoring areas ; the determination of a target species according to different criteria such as wide distribution, limited migration and contact with pollutant-rich sediments; and the selection of suitable parameters. This paper concerns the strategy adopted for the French coast. Ethoxyresorufin-O-deethylase, a specific cytochrome P450-dependent monooxygenase, measured by a simple microplate assay, was selected as an...
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Ano: 1992 URL: http://archimer.ifremer.fr/doc/00100/21169/18787.pdf
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Le chrome en milieu marin ArchiMer
Chiffoleau, Jean-francois.
This document constitutes a synthesis of current knowledge on the chromium biogeochemical cycle. The natural and anthropogenic sources are evaluated, the fluxes between the various geochemical compartments are assessed, with special attention to the riverine and atmospheric inputs to the marine environment. Chromium levels in these compartments are described and show in several areas a very high contamination of marine organisms. Due to the important toxicity of this element, further investigations are absolutely required to better understand its behaviour in the marine environment.
Tipo: Text Palavras-chave: Economic analysis; Air water exchanges; Toxicity; Biogeochemical cycle; Marine environment; Pollution; Chromium.
Ano: 1994 URL: http://archimer.ifremer.fr/doc/1994/rapport-1430.pdf
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Nouvelle méthode de dosage de quelques métaux - traces dans les sédiments et les matières en suspension ArchiMer
Chiffoleau, Jean-francois; Truquet, Isabelle.
Des matières solides séchées sont minéralisées en bombe fermée par un mélange d'acide nitrique, d'acide chlorhydrique et d'acide fluorhydrique à environ 120 °C pendant 180 minutes. Cette attaque acide est totale et le minéralisat liquide obtenu est analysé pour sa teneur en métaux par absorption atomique avec ou sans flamme. C'est une méthode très sensible puisqu'elle permet de détecter dans des particules jusqu'à 0,35 % d'Al; 0,15 % de Fe, 0,1 mg/kg de Cd, 2 mg/kg de Co, 0,4 mg/kg de Cr, 2 mg/kg de Cu, 0,4 mg/kg de Mn, 2 mg/kg de Ni, 2 mg/kg de Pb, 0,1 mg/kg de Zn. La précision de cette méthode, sa reproductibilité ( de l'ordre de 7 % ) et sa facilité de mise en oeuvre en font une méthode de choix pour l'étude de faibles de quantité d'échantillons, comme...
Tipo: Text Palavras-chave: Analyse; Métaux-traces; Sédiments; Matières en suspension; Absorption atomique.
Ano: 1994 URL: http://archimer.ifremer.fr/doc/00140/25119/23228.pdf
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Dragages et environnement marin Etat des connaissances ArchiMer
Alzieu, Claude; Abarnou, Alain; Bassoullet, Philippe; Boutier, Bernard; Chiffoleau, Jean-francois; Crenn, Isabelle; Derrien, Annick; Erard-le Denn, Evelyne; Gourmelon, Michele; Guiliaud, Jean-françois; Silva Jacinto, Ricardo; Le Cann, Pierre; Le Guyader, Françoise; Le Hir, Pierre; L'Yavanc, Jacky; Mauvais, Jean-louis; Menard, Dominique; Michel, Pierre; Monbet, Yves; Pommepuy, Monique; Quiniou, Francoise.
Port activities require continuous or occasional dredging of considerable quantities of sediments : approximately 50 million m3 along the French coastline. A large proportion of the dredgings is authorized for dumping at sea in geographically delimited areas and following an impact evaluation of their potential harmfulness to the marine environment. The environmental risks assessment linked to dredging operations relies on knowledge related to several scientific disciplines contributing to changes in the regulations. This work, intended both for managers and for environmental scientists and engineers, is designed to take stock of the current state-of-the-art in the field of sediment contamination and related ecotoxicological hazards, along with a review of...
Tipo: Text Palavras-chave: Regulations; Management; Impact; Contaminants; Dredging; Réglementation; Gestion; Impact; Contaminants; Dragages.
Ano: 1999 URL: http://archimer.ifremer.fr/doc/1999/rapport-1040.pdf
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Nickel and vanadium contamination of benthic invertebrates following the "Erika" wreck ArchiMer
Chiffoleau, Jean-francois; Chauvaud, Laurent; Amouroux, David; Barats, Aurélie; Dufour, Aurélie; Pecheyran, Christophe; Roux, Nathalie.
Levels of nickel and vanadium, trace metals found in high concentration in the oil spilled from the "Erika" tanker off Brittany (France) in December 1999 (41 +/- 1 and 87 +/- 3 mg kg(-1) respectively), have been monitored over a one-year period following this accidental event in several benthic invertebrates. Ni and V in mussels (Mytilus edulis) and oysters (Crassostrea gigas) soft tissues were analysed twice a month by graphite furnace atomic absorption spectrometry and a scallop (Pecten maximus) shell daily growth bands were sampled every three bands by laser ablation and analysed by ICP-MS for these two contaminants. Survey data for mollusc tissues were compared with reference data arising from the national monitoring database. Ni concentrations in...
Tipo: Text Palavras-chave: Monitoring; Scallop shell; Oyster; Mussel; Vanadium; Nickel; Oil spill.
Ano: 2004 URL: http://archimer.ifremer.fr/doc/2004/publication-402.pdf
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Distribution of silver in mussels and oysters along the French coasts: Data from the national monitoring program ArchiMer
Chiffoleau, Jean-francois; Auger, Dominique; Roux, Nathalie; Rozuel, Emmanuelle; Santini, Anne.
Distribution and behavior of many trace elements in the aquatic environment has been well characterized, but little is known about silver (Ag) concentrations in coastal waters, even though this element ranks among the most toxic to marine invertebrates (Calabrese et al., 1977 ; Fisher and Hook, 1997 ; Webb and Wood, 1998). Studies conducted by Flegal et al. (1995), River-Duarte et al. (1999), and Ndung'u et al. (2001), provided the first valuable data on Ag distribution in the oceanic environment, indicating that this element is found in very low concentrations in the dissolved phase. However, although silver concentrations in coastal waters do not reach the nanomolar range (Smith and Flegal, 1993 ; Squire et al., 2002), formation of a stable chloro...
Tipo: Text Palavras-chave: Mollusks; Coastal water; Silver; Monitoring.
Ano: 2005 URL: http://archimer.ifremer.fr/doc/2005/publication-2553.pdf
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Chemical contamination and sediment toxicity along the coast of Corsica ArchiMer
Galgani, Francois; Chiffoleau, Jean-francois; Orsoni, Valerie; Costantini, Louis; Boissery, P; Calendini, S; Andral, Bruno.
Trace metals (Cd, Pb, Cu, Cr, Ni, Co, Zn, Hg, As, Mn, Al, Fe, and Li) and organic compounds (PCBs, PAHs, lindanes, and DDT and its degradation products) were measured in coastal sediment samples from 27 sites in lagoons and along coastal areas of Corsica. An oyster embryo bioassay evaluated the toxicity of sediments from sites in three coastal lagoons (Urbino, Diane, and Biguglia) and the west coast of Cape Corsica. Despite contamination levels generally lower than those in other Mediterranean coastal areas, contamination is found in specific sites in Corsica and includes natural arsenic contamination on the east coast, insecticide pollution (persistent lindane and DDT) in many areas, both cadmium and lead contamination around Sagone, general contamination...
Tipo: Text Palavras-chave: Corsica; Sediment toxicity; Chemical contamination.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/2006/publication-2169.pdf
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Role of particle sorption properties in the behavior and speciation of trace metals in macrotidal estuaries: The cadmium example ArchiMer
Gonzalez, Jean-louis; Thouvenin, Benedicte; Dange, Catherine; Chiffoleau, Jean-francois; Boutier, Bernard.
The role of particles in the fate and speciation of trace metals in macrotidal estuaries was studied using a surface complexation model (MOCO). Cadmium was selected as the target metal contaminant due to its reactivity in estuaries: cadmium behavior is mainly controlled by heterogeneous processes (sorption/desorption) related to salinity and suspended matter gradients. Various scenarios of suspended matter distribution according to salinity were simulated. The impact of surface properties (specific surface area, density of surface sites, acido-basic properties, and complexation constant) was evaluated using data collected on particles from the Gironde, Loire, and Seine estuaries. Our results show that particle surface properties, evaluated on the basis...
Tipo: Text Palavras-chave: Turbidity maximum; Speciation; Sorption; Particles; Modeling; Macrotidal estuaries; Cadmium.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/2006/publication-2005.pdf
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Hydrocarbon pollution along Moroccan coasts and BPH activity in the mussel Perna perna ArchiMer
Azdi, M.; Moukrim, A.; Burgeot, Thierry; Budzinski, H.; Chiffoleau, Jean-francois; Kaaya, A.; Zekhnini, A.; Narbonne, J. F.; Guarrigues, Ph..
Specimens of the mussel Perna perna were collected along Moroccan coasts to determine the concentrations of polycyclic aromatic hydrocarbons ( PAHs) bioaccumulated in the tissues, and to measure benzo[ a] pyrene hydroxylase (BPH) activity. Chemical analysis of PAHs show that the Mediterranean (Nador, Martil, Tanger) and central Atlantic coasts ( from Rabat to Jorf Lihoudi) are those most contaminated ( 351 245 ng.g(-1) dry weight in Tanger). The mussel contaminants were of mixed origin for most of the locations with non negligible inputs of petrogenic origin in many of them. Baseline levels of PAHs were between 6 and 55 ng.g(-1) dry weight. BPH activity showed significant correlation (r(s) = 0.64, P < 0.05) with total PAH concentrations at the six most...
Tipo: Text Palavras-chave: Mussel; Perna perna; Moroccan coasts; Polycyclic aromatic hydrocarbons; Benzoapyrene hydroxylase; Baseline level.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/00000/10995/12929.pdf
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Modelling Pb and Cd dynamics in the Seine estuary ArchiMer
Thouvenin, Benedicte; Gonzalez, Jean-louis; Chiffoleau, Jean-francois; Boutier, Bernard; Le Hir, Pierre.
The Seine estuary (France) is currently one of the world's most contaminated estuaries, due in particular to its high cadmium and lead content. Proper understanding of contaminant transfer, transformation and retention mechanisms throughout the estuary and up to the adjacent marine zone require a range of studies involving data collections, experiments, and modeling tool. A multivariable transport model (SiAM-3D) was used to simulate dissolved and particulate transport and it is applied to several calculation grids; a speciation model (MOCO) was used to select key species and obtain a schematic system representation. The coupled model for Cd and Pb was compared with field measurements. The complementary character of various tools (model applied to annual...
Tipo: Text Palavras-chave: 3D modeling; Cd and Pb trace metals; Seine estuary.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/publication-3009.pdf
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Metal concentrations in sediment and Nereis diversicolor in two Moroccan lagoons: Khnifiss and Oualidia ArchiMer
Idardare, Zaina; Chiffoleau, Jean-francois; Moukrim, A; Alla, A; Auger, Dominique; Lefrere, L; Rozuel, Emmanuelle.
Metal concentrations were measured monthly during an annual cycle (December 2004 to January 2006) in the tissues of Nereis diversicolor ragworms and sediment from two Moroccan Atlantic coastal lagoons: Oualidia in the north, situated in a highly industrialised urban area and Khnifiss in the south, far from anthropogenic influences. Relatively high levels of Zn, Ag and Cd were found in the sediment of Oualidia lagoon, while Ni concentrations were shown to be high at Khnifiss. The significant metal levels at Oualidia are a result of industrial and urban discharges, coupled with discharges from adjacent phosphate ore processing plants. Trace metal concentrations in worms vary according to season; they are usually high in winter and spring, in relation to the...
Tipo: Text Palavras-chave: Morocco; Coastal lagoons; Sediments; Nereis diversicolor; Metals.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-6127.pdf
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Interactions between Volatile Reduced Sulfur Compounds and Metals in the Seine Estuary (France) ArchiMer
Cozic, Amandine; Viollier, E; Chiffoleau, Jean-francois; Knoery, Joel; Rozuel, Emmanuelle.
Concentrations of volatile hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary (France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum concentrations were 0.80 nM for H2S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver-VRSC conditional stability constants. Major interactions were observed between H2S and...
Tipo: Text Palavras-chave: Conditional stability constant; Metal; Volatile reduced sulfur compounds; Seine estuary.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-5019.pdf
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Monitoring of trace metal contamination in the Souss estuary (South Morocco) using the clams Cerastoderma edule and Scrobicularia plana ArchiMer
Anajjar, E; Chiffoleau, Jean-francois; Bergayou, H; Moukrim, A; Burgeot, Thierry; Cheggour, M.
Concentrations of seven metals (Cd, Cu, Cr, Pb, Ni, Zn, Hg) were monitored monthly during 2 years in two bivalves, Cerastoderma edule and Scrobicularia plana collected from the Souss estuary (South Morocco) before and after the commissioning of a sewage treatment plant in November 2002. According to trace metals, changes in concentrations were observed mainly in S. plana, characterised by a decrease of Cu, Hg and Pb when Cd was clearly increasing. Conversely, no clear changes were observed in C. edule during the same periods. This study suggests the use of S. plana in the monitoring of trace metal contamination of such coastal marine environments.
Tipo: Text Palavras-chave: Monitoring; Waste water; Bivalves; Metals; South estuary.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-4515.pdf
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Changes in the sediment trace metal contamination after the commissioning of a municipal wastewater treatment plant in the Souss estuary (South Morocco) ArchiMer
Moukrim, A; Chiffoleau, Jean-francois; Cheggour, M; Burgeot, Thierry.
Monthly samples of sediment were collected from the Souss estuary, to determine the changes which have occurred in the concentrations of ten metals between 2001 when the low estuary was receiving the wastewaters from Agadir city and 2003 after stopping the sewage dumping. The annual contents of Cu, Fe, Zn (in 2001) and those of Cr, Cu, Fe, Mn, Ni, Pb, and Zn (in 2003) showed significant correlations with those of Al, indicating that fluctuations of their concentrations were only due to those of the aluminosilicate fraction of the clayey sediment. After normalization of these metallic concentrations in relation to those of Al, the contents of the different metals showed insignificant correlations between both years, except for Zn which significantly dropped...
Tipo: Text Palavras-chave: Souss estuary; Wastewater; Sediment; Metal contamination.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-5923.pdf
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First record of butyltin body burden and imposex status in Hexaplex trunculus (L.) along the Tunisian coast ArchiMer
Lahbib, Youssef; Abidli, Sami; Chiffoleau, Jean-francois; Averty, Bernard; El Menif, Najoua Trigui.
We have assessed for the first time the current status of tributyltin (TBT) contamination in Hexaplex trunculus along Tunisian coastal waters. Two sampling campaigns have been performed in July 2004 and July 2007 at seven different sites. The snails were analyzed for imposex status, i.e. Imposex incidence, Relative Penis Length Index (RPLI) and Vas Deferens Sequence Index (VDSI), followed by the quantification of butyltins in their tissues. Imposex was detected in six populations from the 2004 samples and in five populations from the 2007 samples. The imposex incidence ranged from 0 (no imposex) to 100%, the RPLI from 0 to 56.7 and the VDSI from 0 to 4.4. TBT was also detected in six populations in 2004 and five populations in 2007. The concentrations...
Tipo: Text Palavras-chave: Tunisia; Imposex; Hexaplex trunculus; TBT; Tributyltin.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6499.pdf
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